Analysis of Cu(In,Ga)Se2 solar cells: Why performance decreases with increasing Ga content
Identifieur interne : 014258 ( Main/Repository ); précédent : 014257; suivant : 014259
Analysis of Cu(In,Ga)Se2 solar cells: Why performance decreases with increasing Ga content
Auteurs : RBID : Pascal:99-0324149
Descripteurs français
- Pascal (Inist)
- 8460J, Etude expérimentale, Cellule solaire, Cuivre séléniure, Indium séléniure, Gallium séléniure, Molybdène, Contact électrique, Efficacité, Mobilité porteur charge, Réponse spectrale, Spectre visible, Spectre UV, Cuivre composé, Indium composé, Gallium composé, Sélénium composé, Evaluation performance.
- Wicri :
- concept : Molybdène.
English descriptors
- KwdEn :
- Carrier mobility, Copper compounds, Copper selenides, Efficiency, Electric contacts, Experimental study, Gallium compounds, Gallium selenides, Indium compounds, Indium selenides, Molybdenum, Performance evaluation, Selenium compounds, Solar cells, Spectral response, Ultraviolet spectra, Visible spectra.
Abstract
Solar cells have been made from uniform Cu(In,Ga)Se2 films deposited by elemental evaporation with two different Ga compositions, Ga/[In+Ga]=0.30 and 0.65. The solar cells fabricated from these uniform films have 15% efficiency for Ga/[In+Ga]=0.30, but the device efficiency is less than expected for the high Ga content due primarily to a decrease in fill factor and open circuit voltage. Analysis of current-voltage results have shown that the main cause of this decrease is a voltage dependent light generated current, JL,(V). Devices were fabricated with both standard (1 μm) and semi-transparent (0.04 μm) Mo contacts. Bi-facial spectral response measurements were made and analyzed on the devices with the semi-transparent Mo contacts in order to determine the changes in collection efficiency as a function of changing Ga composition and applied voltage. This analysis determined that the decrease in the light generated current with increasing voltage is primarily due to a reduction in minority carrier diffusion length, L, from about 0.8 to 0.1 μm. © 1999 American Institute of Physics.
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Pascal:99-0324149Le document en format XML
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solar cells: Why performance decreases with increasing Ga content</title>
<author><name sortKey="Phillips, J E" uniqKey="Phillips J">J. E. Phillips</name>
<affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Institute of Energy Conversion, University of Delaware, Newark, Delaware 19716-3820</s1>
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<author><name sortKey="Shafarman, W N" uniqKey="Shafarman W">W. N. Shafarman</name>
<affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Institute of Energy Conversion, University of Delaware, Newark, Delaware 19716-3820</s1>
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<term>Experimental study</term>
<term>Gallium compounds</term>
<term>Gallium selenides</term>
<term>Indium compounds</term>
<term>Indium selenides</term>
<term>Molybdenum</term>
<term>Performance evaluation</term>
<term>Selenium compounds</term>
<term>Solar cells</term>
<term>Spectral response</term>
<term>Ultraviolet spectra</term>
<term>Visible spectra</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>8460J</term>
<term>Etude expérimentale</term>
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<front><div type="abstract" xml:lang="en">Solar cells have been made from uniform Cu(In,Ga)Se<sub>2</sub>
films deposited by elemental evaporation with two different Ga compositions, Ga/[In+Ga]=0.30 and 0.65. The solar cells fabricated from these uniform films have 15% efficiency for Ga/[In+Ga]=0.30, but the device efficiency is less than expected for the high Ga content due primarily to a decrease in fill factor and open circuit voltage. Analysis of current-voltage results have shown that the main cause of this decrease is a voltage dependent light generated current, J<sub>L</sub>
,(V). Devices were fabricated with both standard (1 μm) and semi-transparent (0.04 μm) Mo contacts. Bi-facial spectral response measurements were made and analyzed on the devices with the semi-transparent Mo contacts in order to determine the changes in collection efficiency as a function of changing Ga composition and applied voltage. This analysis determined that the decrease in the light generated current with increasing voltage is primarily due to a reduction in minority carrier diffusion length, L, from about 0.8 to 0.1 μm. © 1999 American Institute of Physics.</div>
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<fC01 i1="01" l="ENG"><s0>Solar cells have been made from uniform Cu(In,Ga)Se<sub>2</sub>
films deposited by elemental evaporation with two different Ga compositions, Ga/[In+Ga]=0.30 and 0.65. The solar cells fabricated from these uniform films have 15% efficiency for Ga/[In+Ga]=0.30, but the device efficiency is less than expected for the high Ga content due primarily to a decrease in fill factor and open circuit voltage. Analysis of current-voltage results have shown that the main cause of this decrease is a voltage dependent light generated current, J<sub>L</sub>
,(V). Devices were fabricated with both standard (1 μm) and semi-transparent (0.04 μm) Mo contacts. Bi-facial spectral response measurements were made and analyzed on the devices with the semi-transparent Mo contacts in order to determine the changes in collection efficiency as a function of changing Ga composition and applied voltage. This analysis determined that the decrease in the light generated current with increasing voltage is primarily due to a reduction in minority carrier diffusion length, L, from about 0.8 to 0.1 μm. © 1999 American Institute of Physics.</s0>
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<fC03 i1="17" i2="3" l="ENG"><s0>Selenium compounds</s0>
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<fC03 i1="18" i2="3" l="FRE"><s0>Evaluation performance</s0>
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